Yes this kind of configuration is known as port forwarding. You will need to create a manual NAT rule something like this:
Origsrc=Any
OrigDest=NAT address
OrgService=80
Xlatesrc=Original
XlateDST=WebServer
XlateService=CustomServicePort (or just "Original" if you want to leave it at 80)
Also note if you are "plucking" the NAT address from the "dirty" segment between the firewall's external interface and Internet perimeter router, because you are employing manual NAT you'll need to configure proxy ARP for the NAT address, see sk30197.
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