You didn't say what version of gateway code you are using but the following should apply regardless.
> (the same IPS profile is applied to both clusters)
IPS is probably not your issue then.
> I have specific source and service definitions for the APCL/URLF & AB/AV rulebases
If you want the backup traffic eligible for the Accelerated path you shouldn't do that in your rulebases. First off, do you have a "Log Everything" Any Any Any Accept rule at the bottom of your APCL/URLF policy? You don't need it since the implied cleanup rule is Accept for that policy, so get rid of it. Next you want the backup traffic to not match *anything* in the APCL/URLF policy at all and "fall off the end" of the rulebase (don't worry it will be accepted by default and not logged). Using a specific rule to match that backup traffic will just pull it all into the Medium Path.
For AB/AV policy: An exception will not usually make that traffic eligible for the SXL path, it will only change the decision about whether the matching traffic is "bad" and should be dropped or not. The best way to ensure that the traffic you want is eligible for the SXL path is to put a rule at the top of the TP policy matching the traffic, then in the Action field invoke a profile that has ALL of the Threat Prevention blades unchecked in it. In R80.10 if you have more than one Threat Prevention policy layer (not common), watch out as a match against more than one TP layer will choose the most restrictive action which will almost certainly not be your disabled profile, unless you have added the disabled profile rule to the top of both TP layers.
> I have even disabled the above mentioned blades and it has mode no difference
Once the connection has been assigned a path and it continues to be active, I don't believe disabling various blades and reinstalling policy will suddenly make that existing connection accelerated. New connections of course will potentially now be eligible for the SXL path, but if you are observing a long-running backup connection and are messing around with turning blades on and off I don't think it will have an effect on acceleration.
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